Environmental chemistry

First year, Semester 1

Organic functional groups

Organic functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. These functional groups play a crucial role in organic chemistry because they determine the properties and reactivity of the compounds in which they are found. Each functional group has a specific set of atoms arranged in a particular pattern, and this arrangement gives the group its unique chemical behaviour. Functional groups are used to classify organic compounds and predict their reactivity.

For example, compounds with hydroxyl groups (-OH) are typically alcohols and have certain properties such as solubility in water and the ability to form hydrogen bonds. Similarly, carboxyl groups (-COOH) are found in carboxylic acids, which are known for their acidity and ability to participate in esterification reactions.


Functional Group
Structure
Properties
Example
Hydroxyl Group
-OH
Polar, forms hydrogen bonds
Ethanol (CH3CH2OH)
Aldehyde
-CHO
Polar, reactive
Formaldehyde (HCHO)
Ketone
>C=O
Polar, less reactive than aldehydes
Acetone (CH3COCH3)
Carboxyl Group
-COOH
Highly polar, acidic
Acetic acid (CH3COOH)
Amino Group
-NH2
Basic, forms hydrogen bonds
Aniline (C6H5NH2)
Thiol Group
-SH
More nucleophilic than hydroxyl group
Ethanethiol (CH3CH2SH)
Phosphate Group
-PO4
Highly polar, acidic
ATP
Ether Group
R-O-R
Relatively non-polar
Diethyl ether (CH3CH2OCH2CH3)
Ester Group
-COOR
Polar, pleasant odours
Ethyl acetate (CH3COOCH2CH3)
Amide Group
-CONH2
Polar, forms hydrogen bonds
Acetamide (CH3CONH2)
Nitrile Group
-C≡N
Polar, high dipole moment
Acetonitrile (CH3CN)

This table provides a concise overview of common organic functional groups, highlighting their structures, properties & examples.

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